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8th May 2015 @ 04:35

reaction

Procedure:

SGS 2-1 (1.43 g, 5.6 mmol) was dissolved in DCM (70 mL) and stirred with PIDA (1.77 g, 5.5 mmol) overnight.  Solvent was removed in vacuo

After 24 hours, the solution had turned dark orange and an initial TLC was performed in DCM (Rf = 0.7), and a subsequent TLC was then run in EtOAc with 3% MeOH (Rf = 0.75).  

Conducted by Jason Chami, Evan Hockings, James Kalas, James Manton-Hall, Andreas Orsmond, Mackenzie Shaw and Alex Su.

 

InChI=1S/C12H6ClN5/c13-10-6-15-7-11-16-17-12(18(10)11)9-3-1-8(5-14)2-4-9/h1-4,6-7H

 

TLC

SGS 7-1 tlc